Concern step one. Exactly what mass out of copper would be placed regarding an excellent copper(II) sulphate solution playing with a recent out-of 0.50 An excellent over 10 moments?

Extract the data from the question: electrolyte: copper(II) sulphate solution, CuSO₄ current: I = 0.50 A time: t = 10 seconds F = 96,500 C mol -1 (data sheet)

Estimate the amount of fuel: Q = I x t jeevansathi aansluiting We = 0.fifty An effective t = ten mere seconds Q = 0.fifty ? ten = 5.0 C

Assess this new moles away from electrons: n(age – ) = Q ? F Q = 5.0 C F = 96,five hundred C mol -1 letter(e – ) = 5.0 ? 96,five-hundred = 5.18 ? ten -5 mol

Estimate moles out-of copper using the healthy protection 50 % of response picture: Cu 2+ + 2e – > Cu(s) 1 mole of copper is placed from dos moles electrons (mole proportion) molages(Cu) = ?n(age – ) = ? ? 5.18 ? 10 -5 = dos.59 ? 10 -5 mol

size = moles ? molar size moles (Cu) = 2.59 ? 10 -5 mol molar bulk (Cu) = grams mol -1 (of Periodic Table) mass (Cu) = (2.59 ? ten -5 ) ? = 1.65 ? 10 -3 grams = 1.65 milligrams

Use your calculated value of m(Cu_(s)) and the Faraday constant F to calculate quantity of charge (Q_(b)) required and compare that to the value of Q_(a) = It given in the question. Q_(a) = It = 0.50 ? 10 = 5 C

Make use of your calculated worth of time in mere seconds, new Faraday constant F and also the current offered throughout the matter to help you determine the fresh new bulk from Ag you could put and you will examine you to definitely towards worthy of offered in the concern

Q_(b) = n(e – )F n(e – ) = 2 ? n(Cu) = 2 ? [m(Cu) ? M_r(Cu)] = 2 ? [(1.65 ? 10 -3 ) ? ] = 2 ? 2.6 ? 10 -5 = 5.2 ? 10 -5 mol Q = 5.2 ? 10 -5 ? 96,500 = 5

Concern dos. Calculate the time required to deposit 56 g off silver away from a gold nitrate solution playing with a current regarding cuatro.5 A beneficial.

Assess the brand new moles out-of gold placed: moles (Ag) = bulk (Ag) ? molar size (Ag) bulk Ag deposited = 56 grams molar size = 107

Extract the data from the question: mass silver = m(Ag_(s)) = 56 g current = I = 4.5 A F = 96,500 C mol -1 (from data sheet)

Estimate this new moles off electrons necessary for new reaction: Generate the cures response formula: Ag + + age – > Ag(s) From the picture step one mole from Ag are deposited because of the 1 mole out of electrons (mole ratio) thus 0.519 moles out of Ag(s) try transferred from the 0.519 moles off electrons letter(elizabeth – ) = 0.519 mol

Determine the amount of strength needed: Q = n(elizabeth – ) ? F n(age – ) = 0.519 mol F = 96,five-hundred C mol -step 1 Q = 0.519 ? 96,five-hundred = fifty,083.5 C

Q = It = 4.5 ? 11, = 50083.5 C Q = n(e – )F so, n(e – ) = Q ? F = 50083.5 ? 96,500 = 0.519 mol n(Ag) = n(e – ) = 0.519 mol m(Ag) = n(Ag) ? M_r(Ag) = 0.519 ? 107.9 = 56 g Since this value for the mass of silver is the same as that given in the question, we are reasonably confident that the time in seconds we have calculated is correct.

1. More officially i declare that to own a given amount of energy the amount of substance put are proportional in order to the comparable weight.

Use your calculated value of m(Ag_(s)) and the Faraday constant F to calculate quantity of charge (Q) required and compare that to the value given in the question. n(e – ) = n(Ag) = mass ? molar mass = 0.894 ? 107.9 = 8.29 ? 10 -3 mol Q = n(e – )F = 8.29 ? 10 -3 mol ? 96,500 = 800 C Since this value of Q agrees with that given in the question, we are reasonably confident that our calculated mass of silver is correct.